Thermal degradation of segmented polyurethanes

Synthesis and surface properties of environmentally responsive segmented polyurethanes.

Polyurethanes, containing well-defined assemblies of perfluoro-polyether (PFPE or hexafluoropropene oxide oligomer), polydimethylsiloxane (PDMS), and polyethylene glycol (PEG) segments, exhibit oleophobic, hydrophobic, and hydrophilic properties in response to the polarity of the contacting medium. These polymers were prepared by reacting hydroxy(polyethyleneoxy)-propylether-terminated PDMS blo...

Synthesis of biomimetic segmented polyurethanes as antifouling biomaterials.

Controlling the non-specific adsorption of proteins, cells and bacteria onto biomaterial surfaces is of crucial importance for the development of medical devices with specific levels of performance. Among the strategies pursued to control the interactions between material surfaces and biological tissues, the immobilization of non-fouling polymers on biomaterial surfaces as well as the synthesis...

Degradation of Polyurethanes for Cardiovascular Applications

Study on effective parameters on adhesion in segmented polyurethanes

1. Abstract Phase separation in segmented polyurethanes is an important phenomenon, which affects on characteristic properties of polyurethanes. Morphology, formation and distribution of micro-domains (hard segments and soft segments) are effective parameters on interfacial interaction and adhesion of polyurethane system. In this work segmented polyurethanes based on 4,4 -diphenylmethane diisoc...

Thermal Stability of Aqueous Polyurethanes Depending on the Applied Catalysts

The thermal stability of aqueous polyurethanes has been measured applying the thermogravimetric analysis. The aqueous polyurethanes (aqPUR) with catalysts of different selectivity have been studied by use of the dynamic method. To obtain degradations of 0.025, 0.05, and 0.10, employing the dynamic method, the heating rates of 0.5, 1, 2, 5, and 10 °C min have been used in the range of 30-500 oC....